Seen yes used no.
The area of address space that covers the 3-4gb memory block is allocated to the expansion cards and various bits of hardware. It used to be the top end of the first GB. Some motherboards will allow you to move this block up to a higher point but again only if using a 64bit operating system as otherwise it couldn't access the hardware properly.
Crucial basically say the
same thing . You might get a bit more but it's unpredictable. People with the graphics built into the motherboard will have less than the full amount of memory as the graphics chipset takes from the sub 3GB memory area.
Highest I've seen quoted is 3.2gb which isn't worth the money. If the motherboard can take more than 4gb total then it's probably better to up by 2gb and install a 64 bit OS. Until recently Microsoft were offering windows 7 premium at a pre order price of £45 but that has just jumped to £69.
Let us know what the os claims you have when you plug it in (the value on the general tab of system in control panel not the one when it boots up).
But then unless you are currently using most of the 3gb with some memory hungry software it won't have any effect.