Alien8 said:
Why's that then?
Unless an inner tube has Slime or suchlike in it I would image they have approximately zero puncture resistance regardless of size.
Smaller tubes are stretched more, and much easier to damage than a comparatively unstretched tube. Try cutting a rubber sheet or a bit of old tube with a knife.
examples...
You may have something inside the tyre, like a bit of grit, split rim tape or an exposed spoke hole.
A fragment of glass may have just the very tip getting through the tyre. A small tube will puncture straight away, but a big one may last long enough to show up as a slow puncture that you can fix at home.
A thorn may plug the hole it's just made. I've ridden for over a month with a slow puncture (pump up every other ride) that turned out to be a thorn that had gone a centimetre through the tyre