I have only a few left of the 100 small patches I bought off Mike Dyason (Ozzo) 22 years ago at the Mildenhall rally. They are kept in a drawer of the garage, so the temperature range they are subjected to is between -5C and +40C. They are still good. I've had a few punctures during Winter, and concur the best tube of glue is a new one, however I've been struggling to find a 'puncture outfit' in any of the 'pound' stores. I thought I'd found the 'solution' (pun intended) when I bought a larger-than-normal tube of puncture repair glue from Temu. It's been unused in my garage for a few weeks, and when I punctured last week, I replaced the tube and decided to repair the leaky one after returning home. When I opened the glue I found it was a black substance, and nothing like 'regular' vulcanising glue. On close examination, the script on the reverse of the tube said it was for fixing punctures using rope or similar, and not intended for flat tyres

. Hmm, lesson learned, as they say. An earlier 'buy' from Temu was 10 instant patches, and although I didn't try one on a punctured tube, I tried one on a piece of old inner tube (temp was only 6C in the garage), and just with finger pressure it seemed to adhere enough, and indeed was very difficult to remove!
I'm still on the hunt for tubes of glue, so shall try
Ebay as advised in an earlier note.