I would still say it's a fine adjustment of the H/L limit screws. It can be a real minute turn of one of them and it all falls into place.
Unless of course, your chainrings or front mech are bent.
Just another thought too. Are you running the chain from the middle ring to the extreme of the cassette?
IE: big cog to middle ring or small cog to middle ring. Thus creating a bit of cross chaining.
Nothing terrible about a tiny bit of chain rub. If you adjust it one direction, it'll probably rub in another combination of gears. Shove some nice thick grease on the inside of the front derailleur and stop worrying about it. SRAM's answer (since they don't have electronic trimming) is to make the front cage wider at the end nearest the cassette.
The only adjustment that determines the position of the front mech at the middle front ring is cable tension - so turn the cable tension adjuster while eye-balling the middle cog directly from above until it sits right at the middle of the cage, you are then 99% there. Then try the extreme cogs at the back and see whether it still rub on one side or another, if only rubbing on the outboard side increase the cable tension (i.e. turning the adjuster anti-clockwise) a mite and vice versa.
Cheers for the advice, I think it is now a lot better than it was. I enjoyed messing about with it and learning how it works. Hydraulic brakes are next for a tweak.
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