Pollute how?
In terms of direct, in-use pollution then no - a motorbike emits a cocktail of pollutants including CO2, NOx, HC, CO etc. They also emit a large quantity of H2O which you might not think of as a pollutant but is a relatively high level greenhouse gas. They also emit particulates.
An e-bike emits a little bit of ozone (not good at ground level) and the rider emits CO2, H2O and methane, but in far lower quantities.
Both will give off some particulates from brake and tyre wear, but the motorbike will do much more of this.
The motorbike also generates a regular stream of used fluids (engine oil, occasional fork oil, chain oil fling, brake fluid and coolant).
In terms of direct energy use, no again - a motorbike uses a lot more energy to move itself about, partly down to moving faster, but also down to being heavier. An e-bike uses energy that is generated elsewhere, so the associated pollution is also emitted elsewhere.
In terms of fully wrapped-up, cradle-to-grave emissions - the jury is still out and dependent on a lot of factors such as how long they are used for, where, how, where the raw materials for production came from, how recyclable they are etc.