[QUOTE 5529136, member: 9609"]Would the leading edge of a longer pad not be more likely to dry the rim so the trailing end of the pad could get a better grip ?
I think my biggest error is letting the pads get smooth before replacing them, once they are smooth they become useless in the wet.
may be not, but it's good to know I'm not the only one who struggles with braking in poor conditions. one run last week I was coming down a hill in wet slushy conditions and at best the brakes were just stopping me exceeding 20mph - it's a bit worrying when that happens.[/QUOTE]
It isn't the leading edge that dries the rim, it is heat generated by friction.
No matter how well you wipe water off a smooth surface, a single molecular layer of the water/fluid always remains. This is called a boundary layer and it is holding onto the surface incredibly well. Nothing can wipe it off. The bond is formed through a temporary dipole that attracts the two adjacent molecules of different materials. An excellent example of this tenacious layer is water on glass. No matter how new and sharp your rubber squeegee, a single wipe always leaves a layer of water, albeit thin. This layer clings like hell. A second wipe demonstrates to you that it won't budge, because the squeegee judders and shakes over it. The lubricating second layer is gone, yet the boundary layer remains. It only disappears through evaporation. Wipe your bathroom mirror with a squeegee and see this in action.
Now the same happens with brakes. Nothing wipes the boundary layer, only the adjacent and fluid layers wipe off. The rim now has to heat up before the next layer disappears. This heating happens thanks to the friction between rubber and aluminium. The friction is particularly high between those two materials and the heat generated substantial enough to melt rubber. However, the heat dissipates very quickly and basically just "appears" between pad and rim, elsewhere it quickly disappears, so that even a hot rim is not as hot as just underneath the pad during braking.
In slushy conditions the rim obviously remains cold and further, any friction that is created is negated by the constant supply of icy water around and even on the rim. Slush and snow are particularly bad because it settles on the rim and supplies a steady trickle of lubrication to the rim.
The smoothness of the pad is irrelevant. the round nose of the pad is more important than fake fins and ribs on the braking surface. But like I emphasise, even a sharp, slick, new squeegee cannot do the job of a perfect wipe on a perfectly smooth surface. I think your observation of pad smoothness was skewed by something else, perhaps just observational bias.
Stay out of slush if you can't brake in slush.
Disc brakes obviously avoids some of the contributors to the problem.