I would guess that Pioneer was made around 1992 or thereabouts, so it looks decent enough for it's age.
Generally, on my Pioneers, I tend to use the big front ring the majority of the time when riding on flattish tarmac and I try to come to a halt in second gear, so I can get decent acceleration when the traffic starts moving again. That's the important thing with derailleurs; you need to make a point of changing down before you come to a halt, so you are in the correct starting gear for when you next need to move. It's no good stopping in a high gear, then trying to pull away in a high gear and making a grinding downchange in the middle of a road junction. Unlike a Sturmey Archer 3-speed, where you can pull up at a red light in top gear and change down to 1st whilst stationary before moving off, with a derailleur you always have to be thinking one move ahead. Sometimes, it makes more sense to make a front ring change rather than changing a rear gear, especially if you might run out of gears on the back and need to make a front change later anyway. If I'm approaching the start of a gradient say in the big front ring and the third gear on the back, rather than change to the second gear on the back, I'll usually leave it in the third gear but change to the middle ring. That means if I need to make a further downchange halfway up the gradient, I've still got gears in reserve. You never want to have to do a double-change involving both a front and rear cog at the same time, whilst climbing any sort of gradient as the extra time needed will kill your momentum stone dead.