classic33
Leg End Member
It wasn't the tyre that got hot though, it was the wheel onto which it was fitted. Caused by "a dragging brake".The overheated tyre exploded BECAUSE O2 was present inside the tyre (ie 20% of the gas inside the tyre). If the gas inside the tyre had been N2 (100%) the explosive reaction would not have occurred. As @Cunobelin has quoted:
"The reason for using nitrogen is to eliminate the possibility of a chemical reaction between atmospheric oxygen and volatile isoprene gas (produced by severe heating of the tyre) causing an explosion."