Was definitely not broken before the wheels were retired. Only really keeping them as they are the ones that came on the bike, in case I ever sell it and the new owner wants them.
OK then. Back in the day when I had a wheelbuilding and wheel repair factory, I experienced the same. A sproke broke on a wheel waiting for repair. We all heard it and knowing what it sounds like, knew what it was. It was only found when that wheel's turn on the operating table came.
Spakes break from fatigue and the mode is a travelling stress crack. The crack starts on the outside of the spoke bend and slowly works its way inwards. At some point, the tension in the spoke is too much for the remaining material ahead of the crack and then the crack speeds up. The difference in speed can be seen when you inspect the spoke's broken end with a hand lens. You can see old exposure and new exposure quite clearly.
There is a very, very small change in spoke tension when temperature changes and my guess is that your broken spoke was at the very limit of holding on, the temperature changed (probably increased if we're talking aluminium rims here) and that last straw broke the camel's back.
An aluminium 700c rim will expand in circumference by about 0.5mm if the temperature increases by 10 degrees C.
You can fill in the gaps by figuring out what the conditions were when your spoke broke.