The little canister of talc in a PRK is for dusting the vulanising solution that is not under the repair patch.
It should be brushed away when it has done its job - making the excess solution NON sticky.
Talc or 'releasing compound' INSIDE the inner tube is common and can be forgotten about.
Talc between inner tube and tyre is a no-no. Talc is a self lubricating powdered mineral. Lowest on the Mohr's scale. It will allow the tube to move around inside the tyre and the valve will become 'cocked' over. I never use the valve stem knerled lock ring because when I see the valve 'cocked' over, I know something is wrong. Out comes the tube and it is washed, along with the inside of the tyre.
The joint of a Presta valve where it is held in the tube has been known to come adrift due to the tube shifting around inside the tyre. Difficult to believe, but it happens. Minute ammounts of tyre deformation accumulate over time and cause the inner tube to creep. Especially the rear when climbing a steep hill.
On a Motocross dirt bike, there is a 'security bolt' which helps the tube stay in place.